Christoph Kaul
@christophkaul.bsky.social
Surface & Interfacial Chemistry @ ETH Zurich | CH, DE
Research Focus on Coordination Chemistry, Heterogenous Catalysis, NMR Spectroscopy & Computational Chemistry
Research Focus on Coordination Chemistry, Heterogenous Catalysis, NMR Spectroscopy & Computational Chemistry
Reposted by Christoph Kaul
Rising propylene oxide production intensifies interest in TS-1 and other Ti-zeotype catalysts. New ssNMR and XAS insights into Ti-site structure, peroxo intermediates, defect roles, and hydration effects are advancing molecular-level control over catalyst design.
pubs.acs.org/doi/abs/10.1...
pubs.acs.org/doi/abs/10.1...
Deciphering Active Sites in Titanium Silicalite-1 via Solid-State NMR and X-ray Spectroscopic Signatures
ConspectusPropylene oxide manufacturing has experienced one of the fastest growth rates of commodity chemicals in recent years (ca. 21% from 2020 to 2023) and is expected to reach a market size of 36 ...
pubs.acs.org
December 12, 2025 at 12:57 AM
Rising propylene oxide production intensifies interest in TS-1 and other Ti-zeotype catalysts. New ssNMR and XAS insights into Ti-site structure, peroxo intermediates, defect roles, and hydration effects are advancing molecular-level control over catalyst design.
pubs.acs.org/doi/abs/10.1...
pubs.acs.org/doi/abs/10.1...
Reposted by Christoph Kaul
47/49Ti NMR Crystallography enables to refine the speciation, distortion and distribution of Ti sites in Titanium Silicalite-1, a prominent catalyst for sustainable selective oxidation reactions
doi.org/10.1002/anie...
doi.org/10.1002/anie...
Speciation, Structural Refinement, and Distribution of Ti Sites in Titanium Silicalite‐1 From 47/49Ti NMR Crystallography at 28.2 Tesla
Titanium silicalite-1 (TS-1), used in industrial selective oxidation processes, depends on specific, yet still unresolved Ti sites, dispersed within the framework of an MFI-zeolite. Applying high fie....
doi.org
March 12, 2026 at 5:06 PM
47/49Ti NMR Crystallography enables to refine the speciation, distortion and distribution of Ti sites in Titanium Silicalite-1, a prominent catalyst for sustainable selective oxidation reactions
doi.org/10.1002/anie...
doi.org/10.1002/anie...
Reposted by Christoph Kaul
Our group delegation at ENC-ISMAR to discuss state of the art ssNMR!
April 9, 2025 at 5:10 PM
Our group delegation at ENC-ISMAR to discuss state of the art ssNMR!