Klein-Hessling et al.: Synthesis, spectroscopic and crystallographic characterization of various cymantrenyl thioethers [Mn{C5HxBry(SMe)z}(PPh3)(CO)2] ##CrystalStructure##Cymantrene##Thioether... ##IUCrhttps://journals.iucr.org/paper?S205322962400603X
Synthesis, spectroscopic and crystallographic characterization of various cymantrenyl thioethers [Mn{C5HxBry(SMe)z}(PPh3)(CO)2]
Several manganese complexes of the type [MnCp(PPh3)(CO)2] containing a cyclopentadienyl (Cp) ligand with one to five SMe substituents were prepared and studied by X-ray crystallography. In these structures, a few S⋯S and/or S⋯Br interactions occur, and these are sometimes of significant importance for the arrangement of the molecules in the crystal.
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July 6, 2024 at 12:00 AM
Klein-Hessling et al.: Synthesis, spectroscopic and crystallographic characterization of various cymantrenyl thioethers [Mn{C5HxBry(SMe)z}(PPh3)(CO)2] ##CrystalStructure##Cymantrene##Thioether... ##IUCrhttps://journals.iucr.org/paper?S205322962400603X