Triplet Resting States Govern E/Z Selectivity and Chemoselectivity in Carbene-Pincer Cobalt-Catalyzed Alkyne Semihydrogenation
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November 4, 2026 at 5:12 PM
Triplet Resting States Govern E/Z Selectivity and Chemoselectivity in Carbene-Pincer Cobalt-Catalyzed Alkyne Semihydrogenation
This week's journal club
doi.org/10.1021/jacs...
doi.org/10.1021/jacs...
NHC-Mediated
Olefin Amidoacylation via Amidyl Radical
Intermediates Leading to 5- and 6-Membered Keto-Lactams
Abstract. N-Heterocyclic
carbene (NHC) catalysis has emerged as a versatile
organocatalytic platform for radical-mediated acyl transfer into readily
availa
doi.org
November 2, 2026 at 4:16 AM
This week's journal club
doi.org/10.1021/jacs...
doi.org/10.1021/jacs...
A single-molecule spin–photon interface
www.nature.com/articles/s41...
www.nature.com/articles/s41...
A single-molecule spin–photon interface - Nature
A triplet carbene molecule in a tailored crystal provides a stable single-molecule spin–photon interface with millisecond coherence, advancing chemically engineered molecular qubits for quantum networ...
www.nature.com
October 30, 2026 at 9:54 PM
A single-molecule spin–photon interface
www.nature.com/articles/s41...
www.nature.com/articles/s41...
ICYMI: Now online: Thianthrenium ylides for safe carbene transfer 🧪
Thianthrenium ylides for safe carbene transfer
Nature Synthesis, Published online: 22 October 2026; doi:10.1038/s44160-026-01216-zThianthrenium ylides for safe carbene transfer
go.nature.com
October 29, 2026 at 12:11 PM
ICYMI: Now online: Thianthrenium ylides for safe carbene transfer 🧪
⚛️ Quantum Optics Advance: A novel organic molecular spin-photon interface achieves single-molecule control. Embedding triplet carbene in a host crystal bridges stationary qubits & photons, unlocking scalable quantum networks www.nature.com/articles/s41...
A single-molecule spin–photon interface - Nature
A triplet carbene molecule in a tailored crystal provides a stable single-molecule spin–photon interface with millisecond coherence, advancing chemically engineered molecular qubits for quantum networ...
www.nature.com
October 28, 2026 at 5:39 PM
⚛️ Quantum Optics Advance: A novel organic molecular spin-photon interface achieves single-molecule control. Embedding triplet carbene in a host crystal bridges stationary qubits & photons, unlocking scalable quantum networks www.nature.com/articles/s41...
#ICIQPhD
📚 Thesis defense by Arnau Rodríguez from Prof. Echavarren's group
➡️"Mechanistic Understanding of Transition-Metal-Catalyzed Transformations via Carbene and Vinylidene Species"
📅TOMORROW
🕚10.30 h
Info🔗 iciq.org/event/mechan...
@cerca.cat @bist.eu
📚 Thesis defense by Arnau Rodríguez from Prof. Echavarren's group
➡️"Mechanistic Understanding of Transition-Metal-Catalyzed Transformations via Carbene and Vinylidene Species"
📅TOMORROW
🕚10.30 h
Info🔗 iciq.org/event/mechan...
@cerca.cat @bist.eu
October 29, 2026 at 6:50 AM
#ICIQPhD
📚 Thesis defense by Arnau Rodríguez from Prof. Echavarren's group
➡️"Mechanistic Understanding of Transition-Metal-Catalyzed Transformations via Carbene and Vinylidene Species"
📅TOMORROW
🕚10.30 h
Info🔗 iciq.org/event/mechan...
@cerca.cat @bist.eu
📚 Thesis defense by Arnau Rodríguez from Prof. Echavarren's group
➡️"Mechanistic Understanding of Transition-Metal-Catalyzed Transformations via Carbene and Vinylidene Species"
📅TOMORROW
🕚10.30 h
Info🔗 iciq.org/event/mechan...
@cerca.cat @bist.eu
#ICIQPhD
🎓 Felicitats, Dr. Arnau Rodríguez from Prof. Echavarren's group!
📚He successfully defended his thesis entitled "Mechanistic Understanding of Transition-Metal-Catalyzed Transformations via Carbene and Vinylidene Species"
Read more🔗 iciq.org/new/felicita...
@cerca.cat @bist.eu
🎓 Felicitats, Dr. Arnau Rodríguez from Prof. Echavarren's group!
📚He successfully defended his thesis entitled "Mechanistic Understanding of Transition-Metal-Catalyzed Transformations via Carbene and Vinylidene Species"
Read more🔗 iciq.org/new/felicita...
@cerca.cat @bist.eu
Felicitats, Dr. Rodríguez! - ICIQ
30th October 2026 – Arnau Rodríguez Sugranyes, a PhD student under Prof. Echavarren’s supervision, has successfully defended his thesis today entitled Mechanistic Understanding of Transition-Metal-Cat...
iciq.org
October 30, 2026 at 12:37 PM
#ICIQPhD
🎓 Felicitats, Dr. Arnau Rodríguez from Prof. Echavarren's group!
📚He successfully defended his thesis entitled "Mechanistic Understanding of Transition-Metal-Catalyzed Transformations via Carbene and Vinylidene Species"
Read more🔗 iciq.org/new/felicita...
@cerca.cat @bist.eu
🎓 Felicitats, Dr. Arnau Rodríguez from Prof. Echavarren's group!
📚He successfully defended his thesis entitled "Mechanistic Understanding of Transition-Metal-Catalyzed Transformations via Carbene and Vinylidene Species"
Read more🔗 iciq.org/new/felicita...
@cerca.cat @bist.eu
Air- and Thermally Stable Organometallic Fe(VI) Nitrides Enabled by a Tripodal Mesoionic Carbene Ligand: Access to a Water-Coordinated Fe(VI) Nitrido Complex
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October 26, 2026 at 8:35 AM
Air- and Thermally Stable Organometallic Fe(VI) Nitrides Enabled by a Tripodal Mesoionic Carbene Ligand: Access to a Water-Coordinated Fe(VI) Nitrido Complex
Faster deep-blue Ir(III): Li et al. (Light Sci. Appl. 2026) add CF3 to the carbene ligand to give the triplet charge-transfer character. CF3-2 OLED: 443 nm, CIE (0.147, 0.089), EQEmax 29.0%. doi:10.1038/s41377-026-02264-y
www.lumorachemicals.com/category/iri...
www.lumorachemicals.com/category/iri...
Iridium Complexes · LUMORA
Iridium(III) complexes are phosphorescent emitters used in OLED research, covering red, green, yellow and blue emission depending on the ligands. 112 products with CAS number and purity. Request a quo...
www.lumorachemicals.com
October 28, 2026 at 5:20 AM
Faster deep-blue Ir(III): Li et al. (Light Sci. Appl. 2026) add CF3 to the carbene ligand to give the triplet charge-transfer character. CF3-2 OLED: 443 nm, CIE (0.147, 0.089), EQEmax 29.0%. doi:10.1038/s41377-026-02264-y
www.lumorachemicals.com/category/iri...
www.lumorachemicals.com/category/iri...
For the HQP Highlight Series, we welcome Dr. Ahmadreza Nezamzadeh (C2MCI Macro & Nano HQP with @cathleencrudden.bsky.social) to discuss his work in N-heterocyclic carbene surface chemistry and nanomaterials research.
➡️ Read the full interview: bit.ly/4il386T
#NFRF #ChemSky
➡️ Read the full interview: bit.ly/4il386T
#NFRF #ChemSky
October 26, 2026 at 4:04 PM
For the HQP Highlight Series, we welcome Dr. Ahmadreza Nezamzadeh (C2MCI Macro & Nano HQP with @cathleencrudden.bsky.social) to discuss his work in N-heterocyclic carbene surface chemistry and nanomaterials research.
➡️ Read the full interview: bit.ly/4il386T
#NFRF #ChemSky
➡️ Read the full interview: bit.ly/4il386T
#NFRF #ChemSky
#Chemsky
So, if you see a protocol that says they used KHMDS as a base, and the reaction was conducted in DCM...
Thoughts? Mine are, Holy Fucking Carbene Batman! But am I overreacting? Is this normal?
So, if you see a protocol that says they used KHMDS as a base, and the reaction was conducted in DCM...
Thoughts? Mine are, Holy Fucking Carbene Batman! But am I overreacting? Is this normal?
October 23, 2026 at 3:46 PM
#Chemsky
So, if you see a protocol that says they used KHMDS as a base, and the reaction was conducted in DCM...
Thoughts? Mine are, Holy Fucking Carbene Batman! But am I overreacting? Is this normal?
So, if you see a protocol that says they used KHMDS as a base, and the reaction was conducted in DCM...
Thoughts? Mine are, Holy Fucking Carbene Batman! But am I overreacting? Is this normal?
www.organic-chemistry.org/abstracts/li...
A highly enantioselective carbene insertion into the N-H bonds of sulfonamides provides α-amino esters in good yields with excellent enantioselectivity.
A highly enantioselective carbene insertion into the N-H bonds of sulfonamides provides α-amino esters in good yields with excellent enantioselectivity.
October 23, 2026 at 10:56 AM
www.organic-chemistry.org/abstracts/li...
A highly enantioselective carbene insertion into the N-H bonds of sulfonamides provides α-amino esters in good yields with excellent enantioselectivity.
A highly enantioselective carbene insertion into the N-H bonds of sulfonamides provides α-amino esters in good yields with excellent enantioselectivity.
Now online: Thianthrenium ylides for safe carbene transfer 🧪
Thianthrenium ylides for safe carbene transfer
Nature Synthesis, Published online: 22 October 2026; doi:10.1038/s44160-026-01216-zThianthrenium ylides for safe carbene transfer
go.nature.com
October 22, 2026 at 12:09 PM
Now online: Thianthrenium ylides for safe carbene transfer 🧪
Visible-Light-Driven N-Heterocyclic Carbene Catalysis: Recent Advances in Photocatalyst-Free Radical Transformations https://www.sciencedirect.com/science/article/pii/S0040402026003662
October 22, 2026 at 1:10 AM
Visible-Light-Driven N-Heterocyclic Carbene Catalysis: Recent Advances in Photocatalyst-Free Radical Transformations https://www.sciencedirect.com/science/article/pii/S0040402026003662
www.organic-chemistry.org/abstracts/li...
A general rhodium-catalyzed formal [3 + 2] cycloaddition of vinylcarbenes with nitriles using α-trifluoromethyl vinyl triftosylhydrazones as carbene precursors
A general rhodium-catalyzed formal [3 + 2] cycloaddition of vinylcarbenes with nitriles using α-trifluoromethyl vinyl triftosylhydrazones as carbene precursors
October 20, 2026 at 2:04 PM
www.organic-chemistry.org/abstracts/li...
A general rhodium-catalyzed formal [3 + 2] cycloaddition of vinylcarbenes with nitriles using α-trifluoromethyl vinyl triftosylhydrazones as carbene precursors
A general rhodium-catalyzed formal [3 + 2] cycloaddition of vinylcarbenes with nitriles using α-trifluoromethyl vinyl triftosylhydrazones as carbene precursors
Universitat Wien (@univie.ac.at) is hiring:
University Assistant Predoctoral - Carbene Stabilized Nano Materials and Composites
#phd #chemsky #nanomaterials
University Assistant Predoctoral - Carbene Stabilized Nano Materials and Composites
#phd #chemsky #nanomaterials
October 17, 2026 at 8:28 AM
Universitat Wien (@univie.ac.at) is hiring:
University Assistant Predoctoral - Carbene Stabilized Nano Materials and Composites
#phd #chemsky #nanomaterials
University Assistant Predoctoral - Carbene Stabilized Nano Materials and Composites
#phd #chemsky #nanomaterials
Job ID: 6311
Extract: The University of Vienna seeks a University Assistant Predoctoral for a PhD position focusing on carbene stabilized nanomaterials and composites. The role involves research, teaching, and administration in an interdisciplinary team.
Extract: The University of Vienna seeks a University Assistant Predoctoral for a PhD position focusing on carbene stabilized nanomaterials and composites. The role involves research, teaching, and administration in an interdisciplinary team.
October 17, 2026 at 8:28 AM
Job ID: 6311
Extract: The University of Vienna seeks a University Assistant Predoctoral for a PhD position focusing on carbene stabilized nanomaterials and composites. The role involves research, teaching, and administration in an interdisciplinary team.
Extract: The University of Vienna seeks a University Assistant Predoctoral for a PhD position focusing on carbene stabilized nanomaterials and composites. The role involves research, teaching, and administration in an interdisciplinary team.
Assembly and Encapsulation Properties of Cages Featuring Cofacial Porphyrins and N-Heterocyclic Carbene–Metal Bonds www.chinesechemsoc.org/doi/10.31635...
#chemistry #openaccess #science
#chemistry #openaccess #science
October 14, 2026 at 4:04 PM
Assembly and Encapsulation Properties of Cages Featuring Cofacial Porphyrins and N-Heterocyclic Carbene–Metal Bonds www.chinesechemsoc.org/doi/10.31635...
#chemistry #openaccess #science
#chemistry #openaccess #science
Ariwoola et al. in the Lee Lab at the University of South Carolina build macrocyclic carbazolide-carbene ligands bearing ether or secondary amine donors, forming square-planar Cu(II) complexes. The amine variant shifts the Cu(I)/Cu(II) wave 330 mV more cathodic.
Organometallics
doi.org
October 13, 2026 at 12:22 PM
Ariwoola et al. in the Lee Lab at the University of South Carolina build macrocyclic carbazolide-carbene ligands bearing ether or secondary amine donors, forming square-planar Cu(II) complexes. The amine variant shifts the Cu(I)/Cu(II) wave 330 mV more cathodic.
www.organic-chemistry.org/abstracts/li...
A N-heterocyclic carbene (NHC)-catalyzed synthesis of N-substituted isoindolinone acetates proceeds through a tandem imine umpolung-intramolecular aza-Michael addition followed by oxidation.
A N-heterocyclic carbene (NHC)-catalyzed synthesis of N-substituted isoindolinone acetates proceeds through a tandem imine umpolung-intramolecular aza-Michael addition followed by oxidation.
October 12, 2026 at 7:31 PM
www.organic-chemistry.org/abstracts/li...
A N-heterocyclic carbene (NHC)-catalyzed synthesis of N-substituted isoindolinone acetates proceeds through a tandem imine umpolung-intramolecular aza-Michael addition followed by oxidation.
A N-heterocyclic carbene (NHC)-catalyzed synthesis of N-substituted isoindolinone acetates proceeds through a tandem imine umpolung-intramolecular aza-Michael addition followed by oxidation.
Extract: The Technical University of Chemnitz seeks a Postdoc in Inorganic Molecular Chemistry for a 30-month project on bis(carbene) analogues of aluminium and gallium. Candidates should have a PhD in inorganic chemistry and experience in molecular synthesis and characterization.
October 11, 2026 at 11:30 PM
Extract: The Technical University of Chemnitz seeks a Postdoc in Inorganic Molecular Chemistry for a 30-month project on bis(carbene) analogues of aluminium and gallium. Candidates should have a PhD in inorganic chemistry and experience in molecular synthesis and characterization.