Completed in 2023 in Shanghai, China. Images by CreatAR Images . 1. To Be A Contemporary Community Park Tianlin Park, initially a fenced-off green space named "Tianlin Central Green Land", was built in 1999. As a...

Multinary chalcogenide semiconductors have the potential for use in various optoelectronic and energy-conversion applications. Understanding how to controllably synthesize these semiconductors is paramount to successful device integration. In this report, we analyze the hydrothermal synthesis technique used to make the quaternary sulfide Ag2(NH4)AsS4, focusing on how solvent volume, synthesis time, sulfur background pressure, and initial cation stoichiometry impact the synthesis result. Achieving a reliable synthesis procedure, we characterize the thermal and air stability, calculate the electronic band structure, and measure the optical absorption of Ag2(NH4)AsS4. The sulfide is found to be relatively stable to air exposure at room temperature but is susceptible to thermal decomposition at temperatures below the typical synthesis point (∼220 °C). Ab initio molecular dynamics simulations show that the NH4+ cation can rotate freely within the structure, and single crystal X-ray analysis of Ag2(NH4)AsS4 shows no structural transitions over the temperature range 135–298 K. Hybrid density functional theory calculations indicate that Ag2(NH4)AsS4 is an indirect band gap semiconductor with dispersive band edges, while optical spectroscopy reveals a 2.05(5) eV band gap. The thorough synthesis and materials characterization studies pursued here lay a foundation for film processing of Ag2(NH4)AsS4 and the exploratory synthesis of related quaternary chalcogenides.