##NHeterocyclicCarbene
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gargis.bsky.social
Happy to share our recent work on naphthalene based diradicaloid
#cobatocene #Nheterocycliccarbene
#fluorine
November 20, 2024 at 9:23 PM
sengroup.bsky.social
Wished to make diradicaloids based on perfluoronaphthalene, but a beautiful Co complex was obtained during the reduction with cobaltocene. Happy to publish it in Dalton Transactions. Have a read!
#Nheterocycliccarbene
pubs.rsc.org/en/content/a...
Unprecedented C–F bond cleavage in perfluoronaphthalene during cobaltocene reduction
The C–F bond activation of perfluoronaphthalene by 5-SIDipp led to the formation of dicationic salts with two fluorides (3·2HF2 ) or heptafluorodiborate (3·2B2F7) as counter-anions. The anion exchange...
pubs.rsc.org
November 15, 2024 at 3:43 AM
actacrystc.iucr.org
Schlachta et al.: Formation of a di­iron–(μ-η1:η1-CN) com­plex from aceto­nitrile solution ##OrganometallicIronIIComplex##AcetonitrileCleavage##NHeterocyclicCarbene... ##IUCrhttps://journals.iucr.org/paper?S2053229624007058
Formation of a di­iron–(μ-η1:η1-CN) com­plex from aceto­nitrile solution
A di­iron end-on μ2-η1:η1-CN-bridged com­plex is obtained from a crystallization experiment of an open-chain iron–NHC com­plex. The cyanide appears to originate from the aceto­nitrile (MeCN) solvent by C—C bond cleavage or through carbon–hy­dro­gen oxidation.
journals.iucr.org
August 9, 2024 at 12:00 AM
iucrdata.iucr.org
M​alek and Arumugam: μ-Chlorido-bis­{[1-benzyl-3-(2,4,6-tri­methyl­phen­yl)imidazol-2-yl­idene-κC]silver(I)} chloride 1,2-di­chloro­ethane hemisolvate ##CrystalStructure##NHeterocyclicCarbene##SilverChloride... ##IUCrhttps://journals.iucr.org/paper?S2414314624008617
μ-Chlorido-bis­{[1-benzyl-3-(2,4,6-tri­methyl­phen­yl)imidazol-2-yl­idene-κC]silver(I)} chloride 1,2-di­chloro­ethane hemisolvate
The solid-state structural analysis of the title compound reveals that the two mol­ecules of bis­(1-benzyl-3-mesitylimidazol-2-yl­idene)silver are connected via a bridging chloride atom. The structure also reveals non-classical inter­molecular hydrogen-bonding inter­actions involving the chloride counter-anion.
journals.iucr.org
September 11, 2024 at 12:00 AM