Schlachta et al.: Formation of a diiron–(μ-η1:η1-CN) complex from acetonitrile solution ##OrganometallicIronIIComplex##AcetonitrileCleavage##NHeterocyclicCarbene... ##IUCrhttps://journals.iucr.org/paper?S2053229624007058
Formation of a diiron–(μ-η1:η1-CN) complex from acetonitrile solution
A diiron end-on μ2-η1:η1-CN-bridged complex is obtained from a crystallization experiment of an open-chain iron–NHC complex. The cyanide appears to originate from the acetonitrile (MeCN) solvent by C—C bond cleavage or through carbon–hydrogen oxidation.
journals.iucr.org
August 9, 2024 at 12:00 AM
Schlachta et al.: Formation of a diiron–(μ-η1:η1-CN) complex from acetonitrile solution ##OrganometallicIronIIComplex##AcetonitrileCleavage##NHeterocyclicCarbene... ##IUCrhttps://journals.iucr.org/paper?S2053229624007058