We report changes in the reactivity profile of a high-spin, terminal ferrous hydroxo complex (EmL)Fe(OH) as a function of oxidation states (i.e., FeII/FeIII). The terminal, high-spin Fe–OH adducts wer...

We analyze the effect of integrated resolution, data scaling, structural refinement, and crystal symmetry on the extracted scattering perturbations and their uncertainties for anomalous (resonant) X-r...

We report the photogeneration and characterization of an open-shell, terminal iron nitrido (EmL)Fe(N) using a sterically encumbered dipyrrin ligand environment. The Fe–N distance in the solid-state, zero-field 57Fe Mössbauer spectrum, and computational analysis are consistent with a triplet electronic ground state of the iron nitrido. Notably, the attenuation of Fe–N multiple bond character through occupying π*Fe–N enables (i) primary C(sp3)–H amination, (ii) H2 cleavage, (iii) aromatic C–C cleavage, and (iv) photocatalytic N-atom transfer reactivity. These modes of reactivity have not previously been observed in low-spin Fe(N) analogues.

Layered materials containing hydrocarbon bilayers capable of transitioning between an ordered and partially disordered state can exhibit large temperature and entropy changes─termed barocaloric effect...

Here, we evaluate halide-free phase-change materials built from common surfactants for solid-state temperature regulation. Considering these and other phase-change materials, we illustrate how their s...

We report herein the synthesis and reactivity of the high-spin iron-hydride cluster [K(C222)][(tbsL)Fe3(μ3–H)]. Direct hydride transfer reaction attempts led to cluster reduction to afford the anionic...