#CHActivation
Gold #catalysis is unlocking new possibilities in C–H functionaliation 🔓 Our review by Pablo Barrio’s group highlights exciting advancements in this field, paving the way for innovative #DrugDiscovery and #Materials science.
#CHActivation

👉 https://buff.ly/4azJQGq
January 30, 2025 at 8:00 AM
Our first article for 2025 just came out in @daltontrans.bsky.social
We demonstrate that pairing iridium or osmium hydrides with hafnium can boost C-H activation performances for catalytic H/D exchange in heteroarenes!
doi.org/10.1039/D4DT...
#organometallics #catalysis #CHactivation
Catalytic H/D Exchange of (Hetero)arenes with Early-Late Polyhydride Heterobimetallic Complexes: Impact of Transition Metal Pairs
Metal-catalyzed hydrogen isotope exchange (HIE) has become a valuable method for incorporating deuterium and tritium into organic molecules, with applications in a wide range of scientific fields. Thi...
doi.org
January 21, 2025 at 10:53 AM
Theoretical Insights into Rare-Earth-Catalyst-Controlled Diastereo- and Enantioselective [3 + 2] Annulation of Aromatic Aldimines with Styrenes | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Luo & co-workers @InorgChem #scandium #styrene #Sc_Ph #catalysis #annulation #CHactivation
February 6, 2025 at 1:23 AM
Atunori Mori and co-researchers at the @kobe-university.bsky.social introduce a novel palladium-catalyzed #benzocyclization protocol that creates valuable quinoline-fused lactams through sequential C–H/N–H functionalization.
➡️ https://tinyurl.com/4s9s7e34
#CHActivation #heterocycles
#BJOC 💎🔓
July 21, 2026 at 1:01 PM
🚨New in Organometallics! @acs.org @pubs.acs.org @organicdivision.org
Combining #DFT +experiment reveal how Rh-catalyzed #CHactivation switches mechanisms between CMD and OA. A clear picture of how electronic effects reshape #catalysis.
🔗 pubs.acs.org/doi/10.1021/...
A Change in C–H Activation Mechanism: Experimental and Computational Investigations of Rh-Catalyzed Disubstituted Benzene Functionalization
We report the ethenylation of 1,3- and 1,2-disubstituted benzenes using [(η2-C2H4)2Rh(μ-OAc)]2 as a catalyst precursor and Cu(OPiv)2 as the oxidant. The regioselectivity of alkenylation for 1,3-disubs...
pubs.acs.org
October 29, 2025 at 9:49 PM
🔔 Research article by Suckchang Hong 𝘦𝘵 𝘢𝘭.

One-pot access to quinoline–chalcone hybrids via the iron-catalyzed aerobic oxidative sp³ C–H activation of unactivated alkylquinolines
🔗 doi.org/10.1039/d6qo...

#IronCatalysis #CHActivation #Quinolines #Chalcones #OrganicSynthesis #SustainableChemistry
August 17, 2026 at 3:28 AM
🔔 Research article by Prasad V. Bharatam 𝘦𝘵 𝘢𝘭.

Accessing diverse N-centered peri fused cycles (NCPCs): Rh(iii) catalyzed generation of triazaacenaphthylenes through C-5(H) activation of imidazo[1,2-a]pyridine
🔗 doi.org/10.1039/d6qo...

#CHActivation #RhodiumCatalysis #Heterocycles
August 14, 2026 at 7:35 AM
Many thanks and congratulations to Tingting and @JassminLahbi for this very nice article. Good job ladies! #CHActivation #catalysis #palladium #sulfones @rocs_ipcm @IPCM_Sorbonne @Sorbonne_Univ_ @ScienceSorbonne @INC_CNRS

x.com/EurJOC/status/…
January 20, 2025 at 11:23 AM
#Benzimidazole breakthroughs in our Account by Sun & Pawar✨ Rh/Pd-catalyzed C–H activation + N–H DG enables diverse C–C, C–N, C–O & C–F bond formations using diazo, alkynes, maleimides & more🚀
#CHActivation

👉 buff.ly/T57Emm1
October 3, 2025 at 7:01 AM
Dive into the vibrant chemistry of #nitroarenes 💥 Saroj Ranjan De & co-workers highlight recent advances in regiospecific ortho-nitration of protected anilines, a cleaner, smarter route to key intermediates for dyes, drugs & materials⚗️
#anilines #CHActivation

👉 buff.ly/GeQ4lqI
December 3, 2025 at 8:01 AM